{"dcterms:modified":"2023-07-19","dcterms:creator":"DR-NTU (Data)","@type":"ore:ResourceMap","@id":"https://researchdata.ntu.edu.sg/api/datasets/export?exporter=OAI_ORE&persistentId=doi:10.21979/N9/BWMJDV","ore:describes":{"citation:depositor":"Giovanni, David","kindOfData":["Experimental raw data (*txt)","Analysis data (*xlsx and *opj)"],"subject":"Physics","title":"Replication Data for:  Tunable room-temperature spin-selective optical Stark effect in solution-processed layered halide perovskites","dateOfDeposit":"2019-05-31","citation:dsDescription":{"citation:dsDescriptionValue":"Ultrafast spin manipulation for opto–spin logic applications requires material systems that have strong spinselective light-matter interaction. Conventional inorganic semiconductor nanostructures [for example, epitaxial II-VI quantum dots and III-V multiple quantum wells (MQWs)] are considered forerunners but encounter challenges such as lattice matching and cryogenic cooling requirements. Two-dimensional halide perovskite semiconductors, combining intrinsic tunable MQW structures and large oscillator strengths with facile solution processability, can offer breakthroughs in this area. We demonstrate novel room-temperature, strong ultrafast spin-selective optical Stark effect in solution-processed (C6H4FC2H4NH3)2PbI4 perovskite thin films. Exciton spin states are selectively tuned by ~6.3 meV using circularly polarized optical pulses without any external photonic cavity (that is, corresponding to a Rabi energy of ~55 meV and equivalent to applying a 70 T magnetic field), which is much larger than any conventional system. The facile halide and organic replacement in these perovskites affords control of the dielectric confinement and thus presents a straightforward strategy for tuning light-matter coupling strength","citation:dsDescriptionDate":"2016-06-17"},"author":[{"citation:authorName":"Giovanni, David","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-2764-5613"},{"citation:authorName":"Chong, Wee Kiang","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0001-6059-3918"},{"citation:authorName":"Dewi, Herlina Arianita","citation:authorAffiliation":"Nanyang Technological University"},{"citation:authorName":"Thirumal, Krishnamoorthy","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-9217-8089"},{"citation:authorName":"Neogi, Ishita","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-7707-0512"},{"citation:authorName":"Ramesh, Ramamoorthy","citation:authorAffiliation":"University of California, Berkeley"},{"citation:authorName":"Mhaisalkar, Subodh","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-9895-2426"},{"citation:authorName":"Mathews, Nripan","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0001-5234-0822"},{"citation:authorName":"Sum, Tze Chien","citation:authorAffiliation":"Nanyang Technological University","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0003-4049-2719"}],"citation:keyword":[{"citation:keywordValue":"Optical Stark Effect"},{"citation:keywordValue":"Perovskites"},{"citation:keywordValue":"Spin"},{"citation:keywordValue":"Spintronic"}],"publication":{"publicationCitation":"Giovanni, D., Chong, W. K., Dewi, H. A., Thirumal, K., Neogi, I., Ramesh, R., ... & Sum, T. C. (2016). Tunable room-temperature spin-selective optical Stark effect in solution-processed layered halide perovskites. Science advances, 2(6), e1600477.","publicationIDType":"doi","publicationIDNumber":"10.1126/sciadv.1600477","publicationURL":"https://advances.sciencemag.org/content/2/6/e1600477"},"citation:datasetContact":[{"citation:datasetContactName":"Giovanni, David","citation:datasetContactAffiliation":"Nanyang Technological University"},{"citation:datasetContactName":"Sum, Tze Chien","citation:datasetContactAffiliation":"Nanyang Technological University"}],"grantNumber":[{"citation:grantNumberAgency":"Nanyang Technological University","citation:grantNumberValue":"start-up grants M4080514"},{"citation:grantNumberAgency":"Nanyang Technological University","citation:grantNumberValue":"start-up grants M4081293"},{"citation:grantNumberAgency":"Ministry of Education (MOE)","citation:grantNumberValue":"Academic Research Funding Tier 1 grants RG184/14"},{"citation:grantNumberAgency":"Ministry of Education (MOE)","citation:grantNumberValue":"Academic Research Funding Tier 1 grants RG101/15"},{"citation:grantNumberAgency":"Ministry of Education (MOE)","citation:grantNumberValue":"Tier 2 grants MOE2013-T2-1-081"},{"citation:grantNumberAgency":"Ministry of Education (MOE)","citation:grantNumberValue":"Tier 2 grants MOE2014-T2-1-044"},{"citation:grantNumberAgency":"National Research Foundation  (NRF)","citation:grantNumberValue":"grant NRF-CRP14-2014-03"},{"citation:grantNumberAgency":"Agency for Science, Technology and Research (A*STAR)","citation:grantNumberValue":"Grant 11235100003"}],"software":[{"citation:softwareName":"Microsoft Excel","citation:softwareVersion":"2013"},{"citation:softwareName":"OriginLab","citation:softwareVersion":"9.0"}],"@id":"doi:10.21979/N9/BWMJDV","@type":["ore:Aggregation","schema:Dataset"],"schema:version":"2.0","schema:name":"Replication Data for: Tunable room-temperature spin-selective optical Stark effect in solution-processed layered halide perovskites","schema:dateModified":"Tue Jul 12 17:17:48 SGT 2022","schema:datePublished":"2019-05-31","schema:license":"http://creativecommons.org/licenses/by-nc/4.0","dvcore:fileTermsOfAccess":{"dvcore:fileRequestAccess":false},"schema:includedInDataCatalog":"DR-NTU (Data)","ore:aggregates":[{"schema:description":"Compilation of all raw data and analysis grouped based on figures in the publication.","schema:name":"Raw Data - Sci Adv Vol. 2, no. 6, e1600477.rar","dvcore:restricted":false,"schema:version":1,"dvcore:datasetVersionId":975,"@id":"https://researchdata.ntu.edu.sg/file.xhtml?fileId=10174","schema:sameAs":"https://researchdata.ntu.edu.sg/api/access/datafile/10174","@type":"ore:AggregatedResource","schema:fileFormat":"application/x-rar-compressed","dvcore:filesize":12299215,"dvcore:storageIdentifier":"file://16b0bb2e1fd-2ce426523bbe","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"8c0b4f7e57da9d733e33f54ceccb5287"}}],"schema:hasPart":["https://researchdata.ntu.edu.sg/file.xhtml?fileId=10174"]},"@context":{"author":"http://purl.org/dc/terms/creator","authorIdentifier":"http://purl.org/spar/datacite/AgentIdentifier","authorIdentifierScheme":"http://purl.org/spar/datacite/AgentIdentifierScheme","citation":"https://dataverse.org/schema/citation/","dateOfDeposit":"http://purl.org/dc/terms/dateSubmitted","dcterms":"http://purl.org/dc/terms/","dvcore":"https://dataverse.org/schema/core#","grantNumber":"https://schema.org/sponsor","kindOfData":"http://rdf-vocabulary.ddialliance.org/discovery#kindOfData","ore":"http://www.openarchives.org/ore/terms/","publication":"http://purl.org/dc/terms/isReferencedBy","publicationCitation":"http://purl.org/dc/terms/bibliographicCitation","publicationIDNumber":"http://purl.org/spar/datacite/ResourceIdentifier","publicationIDType":"http://purl.org/spar/datacite/ResourceIdentifierScheme","publicationURL":"https://schema.org/distribution","schema":"http://schema.org/","software":"https://www.w3.org/TR/prov-o/#wasGeneratedBy","subject":"http://purl.org/dc/terms/subject","title":"http://purl.org/dc/terms/title"}}